Long-slit optical spectra show that the northern member (NGC 4496A) of the binary galaxy VV 76 has a systemic velocity of cz = 1700 km s-1^, whereas the southern member (NGC 4496B) has the considerably higher velocity of cz = 4510 km s-1^. A series of three narrow-band CCD images confirms the presence of two distinct redshift systems, showing that the galaxies form an optical, rather than a physical, binary. The probability of a chance superposition is roughly 0.006, not so small that the cosmological interpretation of galaxy redshifts need seriously be questioned. We also report the discovery of a probable Type II supernova (SN 1988M) in NGC 4496B, ~ 200-400 days past maximum brightness. If this object were actually at the distance of NGC 4496A, but with a discordant redshift, it should have been quite bright (mV_~ 13.5-14 mag, neglecting extinction) near maximum and, therefore, likely to have been discovered during several active, systematic searches for supernovae. Since SN 1988M was not detected earlier, we conclude that NGC 4496B is indeed much more distant than NGC 4496A.
The problem of visual texture perception is studied in this thesis. Three texture models are proposed. Each is aimed at exploring a different aspect of the problem. The first model assumes texture is composed of repeating elements. An algorithm is developed to detect, localize, and group these elements into a coherent piece of texture. The assumption of exact repeatedness enables a notion of point to point correspondence, which forms a strong link between the problem of texture and motion/stereopsis analysis. Though texture is widely studied as a 2D phenomenon (tangential texture), nature shows an abundance of relief texture. This 3D nature of texture relates appearance to surface shape in a different way from tangential texture. Moreover, occlusions, shadowing, and mutual illumination have to be taken into account. The geometric aspect of this problem is studied in this thesis through the perpendicular texture model. Intuitive relationships are derived relating the texture and surface properties to the appearance in the image. An example of surface shape recovery is also demonstrated. Finally, a general model for texture is proposed. This is called the texton model. The basic intuition is that, despite the difference in appearance, all textures are made up of symbols from the same vocabulary of tiny prototypical elements. This vocabulary can be learned from example textures. Using this model, a solution to the difficult problem of texture recognition from a single image under any lighting and viewing directions is proposed. This texton model is also used to predict the appearance of natural materials under any illumination and viewing conditions.
Abstract Despite the potentially higher energy density and improved safety of solid-state batteries (SSBs) relative to Li-ion batteries, failure due to Li-filament penetration of the solid electrolyte and subsequent short circuit remains a critical issue. Herein, we show that Li-filament growth is suppressed in solid-electrolyte pellets with a relative density beyond ~ 95%. Below this threshold value, however, the battery shorts more easily as the density increases due to faster Li-filament growth within the percolating pores in the pellet. The microstructural properties (e.g., pore size, connectivity, porosity, and tortuosity) of 75% Li 2 S - 25 P 2 S 5 with various relative densities are quantified using focused ion beam–scanning electron microscopy tomography and permeability tests. Furthermore, modeling results provide details on the Li-filament growth inside pores ranging from 0.2 to 2 µm in size. Our findings improve the understanding of the failure modes of SSBs and provide guidelines for the design of dendrite-free SSBs.
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Synthesis of a series of rhodium complexes bearing a tridentate bis(8-quinolyl)methylsilyl (NSiN) ligand is reported. Bis(8-quinolyl)methylsilane (1) reacted with (PPh3)3RhCl via oxidative addition at the Si−H bond to afford (NSiN)Rh(H)Cl(PPh3) (2). Several coordinatively unsaturated, 16-electron complexes were synthesized, including the cationic complex [(NSiN)Rh(H)(PPh3)][B(C6F5)4] (3) and the neutral complex (NSiN)Rh(CH2Ph)2 (12). The X-ray structures of 3 and 12 reveal a square-pyramidal geometry about the Rh center, with the silyl group occupying an apical position. The dicationic complex [(NSiN)Rh(CH3CN)3][OTf]2 (11), synthesized by reaction of [(NSiN)RhCl2]2 (10) with 2 equiv of AgOTf in acetonitrile, exhibits moderate activity as a catalyst for alkene hydrogenation and for H/Cl exchange between Ph3SiH and CH2Cl2. Complex 2 reacts with 2 equiv of PhCH2MgCl in benzene to afford (NSiN)Rh(CH2Ph)Cl(PPh3) (6). Chlorination of 2 by DBU in CH2Cl2 afforded the solvent-activated Rh(III) product (NSiN)RhCl2(PPh3) (8). Similarly, with PMe3/CH2Cl2 as the chlorinating reagent, [(NSiN)Rh(PMe3)2Cl]Cl (9) was obtained. The low-valent complex (NSiN)Rh(COD) (14; COD = 1,5-cyclooctadiene) was synthesized via the reaction of 1 with (COD)Rh(η3-CH2Ph) in benzene. The COD ligand was replaced by the phosphine-based dppe ligand, resulting in the thermally more stable complex (NSiN)Rh(dppe) (18; dppe = Ph2PCH2CH2PPh2).
Complexes of palladium with the bisphosphine ligand CyPFt-Bu are reported to catalyze the C-S cross-coupling between bromo- or iodoarenes and free thiols in very good to excellent yields and without the formation of side products. The reaction has a broad substrate scope and tolerates a wide range of functional groups.