Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn<sub>4</sub>O(TCA)<sub>2</sub>] Having the Pyrite Topology — Hee K. Chae (2003) | RDL Network
Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn<sub>4</sub>O(TCA)<sub>2</sub>] Having the Pyrite Topology
Article 2003 en
Authors
HC
Hee K. Chae
JK
Jaheon Kim
OF
Olaf Delgado Friedrichs
Abstract
1 min read
Building blocks, octahedral (basic zinc acetate units) and triangular (tritopic carboxylic acid), are assembled into a metal-organic framework (MOF-150) having the topology of the FeS2 pyrite net (see picture). Two independent nets interpenetrate, forming the first example of a fully catenated structure with mixed coordination, an occurrence that is ascribed to the self-dual property of the pyrite net (TCA=4,4′,4′′-Tricarboxytriphenylamine).
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