A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4‘-bpy)<sub>2.5</sub>(H<sub>2</sub>O)<sub>2</sub>(ClO<sub>4</sub>)<sub>2</sub>·1.5(4,4‘-bpy)·2H<sub>2</sub>O — Omar M Yaghi (1997) | RDL Network
A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4‘-bpy)<sub>2.5</sub>(H<sub>2</sub>O)<sub>2</sub>(ClO<sub>4</sub>)<sub>2</sub>·1.5(4,4‘-bpy)·2H<sub>2</sub>O
The hydrothermal reaction of Ni(II) and the rodlike 4,4'-bipyridine ligand yields an extended 1-D noninterpenetrated open framework resembling a railroad with large pores of 11 × 11 Å aperture. (4,4'-Bipyridine is illustrated as lines, and Ni atoms are at the intersections.)
Dan Feng, Wei Luo, Junyong Zhang, Ming Xu, Renyuan Zhang, Haoyu Wu, Yingying Lv, Abdullah Mohamed Asiri, Sher Bahadar Khan, Mohammed M. Rahman, Gengfeng Zheng, Dongyuan Zhao
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