Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology

Hee K. Chae; Jaheon Kim; Olaf Delgado Friedrichs; M. O’Keeffe; Omar M Yaghi

doi:10.1002/ange.200351546

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Omar M Yaghi

University of California, Berkeley

Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology

Article 2003 en

Authors

HC
Hee K. Chae
JK
Jaheon Kim
OF
Olaf Delgado Friedrichs

Abstract

1 min read

Topologisches Lehrstück: Oktaedrische Bausteine (basische Zinkacetat-Template) bauen mit dreieckigen Bausteinen (Tricarbonsäuren) die anorganisch-organische Architektur MOF-150 auf (siehe Bild, links), die der Pyritstruktur (rechts) topologisch entspricht. Die Durchdringung zweier unabhängiger Gitter ergibt die erste vollständig verkettete Struktur mit gemischter Koordination. Entscheidend dafür sind die selbstdualen Eigenschaften der Pyritstruktur (TCA=4,4′,4′′-Tricarboxytriphenylamin).

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Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn<sub>4</sub>O(TCA)<sub>2</sub>] Having the Pyrite Topology

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