ChemInform Abstract: Synthesis and Crystal Structures of the Lithiated Silylphosphanes (CMe3)2SiFP(Mes)Li(THF)3, (CMe3)2SiFLi(TMEDA)PMes, and of the Cyclic Silylphosphanes ((CMe3)2SiPMes)2. — M. ANDRIANARISON (1990) | RDL Network
ChemInform Abstract: Synthesis and Crystal Structures of the Lithiated Silylphosphanes (CMe3)2SiFP(Mes)Li(THF)3, (CMe3)2SiFLi(TMEDA)PMes, and of the Cyclic Silylphosphanes ((CMe3)2SiPMes)2.
ChemInform 21(18)
Article 1990 English
Authors
MA
M. ANDRIANARISON
UK
U. Klingebiel
DS
D. Stalke
Abstract
1 min read
The silylphosphane (III), prepared by reaction of the silane (I) with the lithium phosphide (II), reacts with tert‐butyllithium (IV) in the presence of THF or TMEDA to give the lithium complexes (VI).
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