Oxidation and interdiffusion behaviors of Ni-based single crystal superalloy DD98M with nominal compositions Ni–5.0Co–6.0Cr–6.3Al–6.0W–2.0Mo–6.0Ta–1.0Ti (in wt.%) and two types of MCrAlY coatings at 1000 °C and 1050 °C were investigated. Complex oxides formed on the surface of DD98M alloy when oxidized at 1000 °C and 1050 °C, which stratified, cracked and spalled. The faceted-like AlN and the particle-like and strip-like TiN formed in the alloy. The application of the NiCrAlY and NiCoCrAlYHfSi coatings greatly improved the oxidation resistance of DD98M alloy. After 500 h oxidation, α-Al2O3 was still the dominate phase in the oxide scales formed on the coated specimens. The adhesion of the oxide scale on the NiCoCrAlYHfSi coating was much better than that on the NiCrAlY coating. Interdiffusion occurred between the coatings and the substrate, which led to the formation of the IDZ and SRZ. The IDZ of the NiCrAlY coated specimen was composed of γ phase and Al- and Ta-rich γ′ phase. The γ′ phase in the IDZ accommodated most of the inward diffusing aluminum, so the SRZ formation was suppressed when oxidized at 1050 °C. However the formation of SRZ with μ-TCP still occurred when oxidized at 1000 °C probably due to the low solubility and slow diffusion rate of the alloying elements at lower temperature. The IDZ of the NiCoCrAlYHfSi coated specimen was a single γ phase. A large amount of μ-TCP precipitated in the SRZ of the NiCoCrAlYHfSi coated specimen when oxidized at 1000 °C and 1050 °C. It can be concluded coating composition has a significant effect on the development of the IDZ and SRZ. Thermal exposure temperature also has influences on the formation of the SRZ. The mechanism of SRZ formation and TCP precipitation are discussed.
This study presents the world-first design of solar chimney for a real building considering both energy saving and fire safety. Typical designing factors on both functions were investigated by a numerical tool after it was validated by experiments. It was obtained that solar chimney can be adopted for both functions with 7.42 air changes per hour natural ventilation under normal conditions and at least 6.52 times extension of available safe egress time for occupants under typical fire conditions. It was also known that the previously obtained optimized cavity gap of 0.2–0.3m is no longer applicable for a big space, where the optimum gap is 1.2m considering both functions for a big space. A consistency coefficient is also proposed here that a positive consistency coefficient means the increased parameter can enhance the performance of both functions, while a negative coefficient represents the performance enhancement of one function will compromise the other. The consistency coefficient of those designing parameters are as follows: cavity gap (30.91) > air supply area through top vent (12.47) > air supply area through bottom door (5.4) > cavity height (3.09) > 0 > solar radiation (−0.47) > cavity height below the roof (−40.04). The parameters with negative consistency such as cavity height below the roof should be considered carefully when both functions are planned.
Although natural latex mattresses have been increasingly used in our lives, its high fire risk could put occupants in big danger. Therefore, a series of experiments were carried out to investigate the fire behaviors of natural latex foam with single and laminated layers. Both single and laminated layer samples showed three burning stages: initial acceleration, stable and decaying stages. A fierce burning and bottom ignition were observed at the end of the stable stage for both types. It was known from the experiments that for laminated sample the shrinkage of the thin layers could increase the fire risk as it could accelerate the combustion process, while no obvious difference was found when the number of layers increases from 2 to 5. When comparing to the single layer sample, the laminated layer samples with at least 100 s shorter burning period showed 28.3% higher average flame height, 31.2% higher surface flame spread rate, 92.3% greater peak mass loss rate, and 43.4% higher fuel regression rate along the thickness direction. However, these two types showed a similar maximum flame height, indicating that the maximum flame height may be much dependent on the sample mass but not the shrinkage of the thin layers.
The creep deformation behavior of a single-crystal Co–Al–W–Ni–Cr–Ta alloy with low tungsten content has been studied at stresses between 275 and 310MPa at 900°C. The alloy exhibits comparable creep strength with that of Co–Al–W-base alloys containing more tungsten. The creep deformation consists of three stages, the primary stage, the steady-state stage and the tertiary stage, when described by the creep strain rate versus time curve. At 900°C, γ′ precipitates tend to raft along the direction of applied tensile stress in the steady-state creep stage and a topologically inverted and rafting γ/γ′ microstructure is formed in the tertiary stage. The main deformation mechanism in the primary creep stage is dislocation shearing of γ′ precipitates, and in the following creep stages, the dominant deformation mechanism is dislocations bypassing γ′ precipitates.
In the present paper, a high gain and multiband patch antenna with semi fractal structure is designed. The patch antenna owns a hexagonal shape with the longest diagonal being 52.99mm. At the edge of the patch, an angle was cut to adjust the input impedance characteristics of the antenna as well as minimize its radiation size. We employ the FDTD method to calculate its radiation properties. Results show that the radiation gain can reach 6.95dBi at 2.45GHz with a good radiation pattern, which manifests itself a great potential application in radio frequency identification (RFID) industry.
Electrocatalytic reduction of CO2 (CO2ER) has been recognized as a promising utilization method of CO2. The catalysts are the core of the CO2ER and they have a great influence...
Critical ventilation velocity is an important parameter for the design of road tunnel, while the situation of two fire sources should be considered due to the high probability of two crashed vehicles or fire propagation. The influences of separating distance between two fire sources on the critical ventilation velocity were investigated numerically after the experimental validation of numerical tool. The trend of the dimensionless critical velocity along the separating distance can be divided into three regions, including limited influence, fast decrease, and slight fluctuation. As the separating distance keeps increasing, the fire plumes transform from completely merged to completely separate. The different merging behaviors of fire plumes are the main reasons of showing various critical ventilation velocities with different separating distances. Finally, an empirical model was developed to predict the dimensionless critical ventilation velocity of double fire sources with different separating distances in the longitudinally ventilated road tunnel.
Roof solar chimney is one type of solar chimney to enhance the natural ventilation in buildings. Under the factor that previous studies numerically modelled and validated their results by single test rig, experimental data from all the possible test rigs in the literature were collected and analysed in this study to develop an empirical model for general use. This empirical model was validated by experimental data from various test rigs, with an average error of 14% and up to 144.6% error. Based on the experimental data from different test rigs, the influences of several factors, such as calculated inclination angle (θ′, shown in Eq. (6)), cavity gap (d), width (w), height (H), height/cavity gap ratio (H/d), inlet area (A in ), outlet area (A out ) and radiation heat (q), on solar chimney performance were addressed. The volumetric flow rate of roof solar chimney showed a linear relationship with w(sinθ′)1/3 q 1/2 d 0.7 H 2/3. The slope of this linear relationship can be determined by test environment, cavity material, glazing, and insulation conditions. Those experimental data within a H/d range of 2.5–103.5 showed that the air velocity increases with a larger H/d, but the volumetric flow rate behaves in an opposite way. It is known from experiments that an equal inlet and outlet area can enhance the flow rate in the cavity and for unequal openings the outlet area showed a relatively higher importance in promoting the air flow.
Efficient and sustainable ventilation in urban tunnels is crucial for combating air pollution and safeguarding human health. This study investigates the design factors impacting solar chimney performance in urban tunnels to optimize ventilation efficiency. Experimental trials analyzed the effects of blockage ratio, chimney height, and solar radiation on temperature distribution and ventilation rate. The results demonstrate that increased chimney height and solar radiation positively influence airflow velocity at the chimney outlet, enhancing ventilation. The temperature rise near absorber is higher than that closed to glazing wall. Temperature distribution within the chimney follows a distinctive horizontal two-piecewise semi-parabolic decay pattern, enabling accurate prediction of temperature profiles along the cavity depth. Novel analytical models predict temperature distribution, airflow velocity, and ventilation rate within the solar chimney system, aiding precise design and optimization. Remarkably, the blockage ratio has limited impact on ventilation rate, allowing for disregarding vehicle blockage effects in solar chimney design for urban tunnels. Matching chimney width to tunnel width and ensuring a relatively high chimney height are emphasized for optimal functionality. The study holds substantial implications for ventilation system design in urban environments, promoting healthier and more sustainable cities.
Combustion characteristics of electrolyte pool fires are investigated both theoretically and experimentally under various pan diameters and external heat fluxes using a cone calorimeter. The heat release rate (HRR), mass loss rate (MLR), flame height and gas release rate are measured. Experimental results show that the peak HRR and MLR per unit area are proportional to external heat fluxes and inversely proportional to pan diameters. Dimensionless flame height is observed to decrease under a bigger pan diameter. Peak CO and CO2 production rates increase with a bigger pan diameter or external heat flux, but these two factors show limited influence on the mole ratio of CO/CO2. Comparing to hydrocarbons, the electrolyte has relatively low effective heat of combustion and high heat of gasification which results in lower HRR or MLR, and a higher flame height. An empirical model is developed to predict the peak HRR of the electrolyte pool fire based on pan diameter and external heat flux. Besides, Heskestad's correlation has been improved to predict the average flame height of the electrolyte pool fire by considering the effective heat of combustion, pan diameter and mass stoichiometric ratio of air to fuel.