No abstract is provided for this article.
Numerous of lithium ion battery fires or explosions enhance the need of fire control technology. To investigate the effectiveness of depressurization on the fire suppression of lithium ion batteries in an aircraft environment, an experimental and theoretical study is taken on the ignition and combustion characteristics of lithium ion batteries under an incident heat flux of 50 kW/m2 using a low pressure tank. Several fire parameters are measured and analyzed, including time to deflation, ignition and thermal runaway, surface and flame temperatures as well as average mass loss rate. Experimental results show the average mass loss rate and surface and the peak flame temperatures decrease whereas the time to deflation, ignition and thermal runaway increase with the reduction of the pressure, demonstrating a lower fire risk. The 30 kPa is the critical pressure for the ignition of lithium ion battery under 50 kW/m2 radiation heat flux. However, the pressure shows limited influence on the ignition temperature, radiation coefficient and time interval between the time to ignition and thermal runaway. The effect mechanisms of pressure on fire parameters are revealed. An empirical model is developed to predict the average mass loss rate of lithium ion battery under low atmospheric pressure.
A model to predict carbon monoxide (CO) of woods under external heat flux was developed. To improve the modeling accuracy, fire processes such as water evaporation, volume shrinkage, water and gas transport inside wood slab were considered. Three reactions such as water evaporation, oxidation reactions of virgin wood and char were included. Temperature and moisture dependent thermal properties were used for modeling input. In the second part of this study, this model was validated by experiments. Comparisons between modeling and experiments showed that mass loss rate and CO release rate can be well predicted for woods under different moisture contents and external heat flux. Volume shrinkage, transport processes of water and gas volatiles inside wood slab were also included. This paper serves as validation and application of a mathematical model in Part I: Theory of a model to predict CO of woods under external heat flux. This model intends to provide a practical tool to predict toxic gases of combustible materials under fire conditions.
Silica aerogels (SAs) present great application prospects especially on thermal insulation, but their flammability is usually ignored. A combined study on the combustion behaviors and oxidation kinetics of hydrophobic silica aerogels prepared by ambient pressure drying (SA-apd) and supercritical drying (SA-sd) was performed by employing cone calorimeter and thermal analysis. The whole combustion process for SAs could be divided into three stages in which a fire propagation phenomenon was observed with the radial propagation velocity of 6.68.3cms1. Current investigations forcefully demonstrated that hydrophobic SAs were combustible and easy to flashover when exposed to a heat flux higher than 25kWm2. Compared between the two SAs, the SA-sd owned a less fire risk with presenting a less fire hazard and a lower smoke toxicity than those of SA-apd. The oxidation kinetics by Ozawa-Flynn-Wall method revealed that SA-sd had larger apparent activation energies than those of SA-apd which conformed to the thermal stability analysis by TG-DSC. Furthermore, a two-step combustion mechanism was proposed to explain the combustion behaviors of SAs.
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Although discrete flame spread is a common phenomenon in the practical fire scenarios, such as a group of burning trees under bushfire, research gaps still exist to address the flame spreading criteria and the related spread characteristics. Therefore, through this study, a group of birch rods with different lengths (denoted by l within 60–100 mm) and spacings (S, 1–9 mm) were analyzed experimentally and theoretically. It was known that the critical criterion of discrete flame spreading is determined by the l and S, where a criterion of l≥3d (sample thickness) could predict the critical spacing between the separated birch rods. Theoretical models were also developed to predict the global flame spread rate and mass loss rate under various S and l. The predictions based on the newly developed models agree reasonably well with those experimental data. Global flame spread rate, mass loss rate and flame height increase first and then decrease along with a bigger S, where the dimensionless flame height shows a piecewise exponential relationship with the dimensionless heat release rate. The research outcomes of this study provide a theoretical basis for the fire risk evaluation of those discrete fire spread.
The tensor force is implemented into the time-dependent Hartree-Fock (TDHF) theory so that both exotic and stable collision partners, as well as their dynamics in heavy-ion fusion, can be described microscopically. The role of tensor force on fusion dynamics is systematically investigated for $^{40}\mathrm{Ca}+\mathrm{^{40}Ca}$, $^{40}\mathrm{Ca}+\mathrm{^{48}Ca}$, $^{48}\mathrm{Ca}+\mathrm{^{48}Ca}$, $^{48}\mathrm{Ca}+\mathrm{^{56}Ni}$, and $^{56}\mathrm{Ni}+\mathrm{^{56}Ni}$ reactions which vary by the total number of spin-unsaturated magic numbers in target and projectile. A notable effect on fusion barriers and cross sections is observed by the inclusion of tensor force. The origin of this effect is analyzed. The influence of isoscalar and isovector tensor terms is investigated with the T$IJ$ forces. These effects of tensor force in fusion dynamics are essentially attributed to the shift of low-lying vibration states of colliding partners and nucleon transfer in the asymmetric reactions. Our calculations of above-barrier fusion cross sections also show that tensor force does not significantly affect the dynamical dissipation at near-barrier energies.