Two 2,7-linked carbazole derivatives, 2,7-bis(2-thiophene)-N-methylcarbazole (BTC) and 2,7-bis(2- 3,4-ethylenedioxythiophene)-N-methylcarbazole (BEC), were successfully synthesized and electropolymerized. The electrochemical and optical investigations indicated that the two monomers and their resulting polymers (PBTC and PBEC) showed excellent polymerization and redox activity, and substitution with EDOT units resulted in a decrease in the monomer and polymer oxidation potentials, narrowing of the electronic band gap relative to the corresponding thiophene substituted 2,7-carbazoles. Spectroelectrochemical study revealed that both of the polymers had interesting electrochromic properties and displayed multi-electrochromic behaviors as well as good switching properties. The electrochromic properties of the two polymers are dependent on the selective of substituents attached at the 2,7-positions of N-methylcarbazole. Moreover, dual-type electrochromic devices (ECDs) consisting of PBTC (or PBEC) and PEDOT layers were also fabricated and characterized in detail. It was found that both of the ECDs dispalyed good electrochromic performances, such as reasonable optical contrast, fast response time and excellent redox stability.
Abstract One major challenge for wearable electronics is that the state‐of‐the‐art batteries are inadequate to provide sufficient energy for long‐term operations, leading to inconvenient battery replacement or frequent recharging. Other than the pursuit of high energy density of secondary batteries, an alternative approach recently drawing intensive attention from the research community, is to integrate energy‐generation and energy‐storage devices into self‐charging power systems (SCPSs), so that the scavenged energy can be simultaneously stored for sustainable power supply. This paper reviews recent developments in SCPSs with the integration of various energy‐harvesting devices (including piezoelectric nanogenerators, triboelectric nanogenerators, solar cells, and thermoelectric nanogenerators) and energy‐storage devices, such as batteries and supercapacitors. SCPSs with multiple energy‐harvesting devices are also included. Emphasis is placed on integrated flexible or wearable SCPSs. Remaining challenges and perspectives are also examined to suggest how to bring the appealing SCPSs into practical applications in the near future.