Water‐Stabilized Three‐ and Four‐Atom Palladium Clusters as Highly Active Catalytic Species in Ligand‐Free CC Cross‐Coupling Reactions — Antonio Leyva‐Pérez (2013) | RDL Network
Water‐Stabilized Three‐ and Four‐Atom Palladium Clusters as Highly Active Catalytic Species in Ligand‐Free CC Cross‐Coupling Reactions
Angewandte Chemie International Edition 52(44): 11554-11559
Article 2013 English
Authors
AL
Antonio Leyva‐Pérez
JO
Judit Oliver‐Meseguer
PR
Paula Rubio‐Marqués
Abstract
1 min read
Elite cliques: Palladium clusters with three and four atoms were found to be the catalytically active species for ligand-free palladium-catalyzed CC bond-forming reactions. These palladium cluster species could be stabilized in water and stored for long periods of time for use on demand with no loss of activity. High yields of products and turnover frequencies (TOFs) of up to 10(5) h(-1) were observed.
Estefanía Fernández, Miguel A. Rivero‐Crespo, Irene Domínguez, Paula Rubio‐Marqués, Judit Oliver‐Meseguer, Lichen Liu, María Cabrero‐Antonino, Rafael Gavara, Juan Carlos Hernández‐Garrido, Mercedes Boronat, Antonio Leyva‐Pérez, Avelino Avelino
Judit Oliver‐Meseguer, Lichen Liu, Saray Garcia‐Garcia, Clàudia Canós-Giménez, Irene Domínguez, Rafael Gavara, Antonio Doménech‐Carbó, Patricia Concepción, Antonio Leyva‐Pérez, Avelino Avelino
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