Water‐Stabilized Three‐ and Four‐Atom Palladium Clusters as Highly Active Catalytic Species in Ligand‐Free CC Cross‐Coupling Reactions

Auf kleinstem Nenner: Palladiumcluster mit drei oder vier Atomen erwiesen sich als katalytisch aktive Spezies in ligandenfreien palladiumkatalysierten C-C-Kupplungen (siehe Bild). Die Cluster konnten in Wasser stabilisiert und ohne Aktivitätseinbuße lange Zeit aufbewahrt werden. Hohe Produktausbeuten und Umsatzfrequenzen (TOF) bis 105 h−1 wurden beobachtet. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.