Triazatrimetallabenzenes, a New Class of Inorganic Heterocycles; Synthesis and Structure of [Cp*TaN(Cl)]3

Herbert Plenio; Herbert W. Roesky; Mathias Noltemeyer; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1002/anie.198813301

Triazatrimetallabenzenes, a New Class of Inorganic Heterocycles; Synthesis and Structure of [Cp*TaN(Cl)]3

Angewandte Chemie International Edition 27(10): 1330-1331

Article 1988 English

Abstract

1 min read

Compound 1 may be viewed as a cyclic trimer of a tantalum nitride and provides support for the postulated stability of benzene-like metal nitride trimers. Compound 1 was obtained in 67% yield from [Cp*TaCl4] and N(SnMe3)3 and displays a six-membered ring, which, however, is not fully planar.

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Triazatrimetallabenzenes, a New Class of Inorganic Heterocycles; Synthesis and Structure of [Cp<sup>*</sup>TaN(Cl)]<sub>3</sub>

Abstract

Discussion(0)

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