A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl<sub>3</sub>WN<sub>3</sub>(PPh<sub>2</sub>)<sub>2</sub>] — Herbert W. Roesky (1986) | RDL Network
A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl<sub>3</sub>WN<sub>3</sub>(PPh<sub>2</sub>)<sub>2</sub>]
Angewandte Chemie International Edition 25(5): 477-478
Article 1986 English
Authors
HR
Herbert W. Roesky
KK
Kattesh V. Katti
US
Ulrich Seseke
Abstract
1 min read
A six-membered planar WN3P2 ring characterizes the structure of the title compound 3; probably a chlorine-bridged polymer is present in the solid state. The yellow phosphazene 3 is formed upon reaction of tungsten hexachloride 1 with the salt 2 in chloroform.
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