Synthesis and Structure of [CIV(OSiMe<sub>3</sub>)N<sub>2</sub>PPh<sub>2</sub>]<sub>2</sub>, the First Cyclodimetallaphosphazene–an Eight‐Membered Planar Unsaturated Heterocycle — Michael Witt (1988) | RDL Network
Synthesis and Structure of [CIV(OSiMe<sub>3</sub>)N<sub>2</sub>PPh<sub>2</sub>]<sub>2</sub>, the First Cyclodimetallaphosphazene–an Eight‐Membered Planar Unsaturated Heterocycle
Angewandte Chemie International Edition 27(6): 850-851
Article 1988 English
Authors
MW
Michael Witt
HR
Herberi W. Roesky
MN
Mathias Noltemeyer
Abstract
1 min read
The heterocyclic moiety of 2 is an 8π-electron system, yet planar. The divanadacyclophosphazene 2 is a brick-red compound formed in 80% yield upon reaction of VOCl3 with 1. The heterocycle 2 is thermally very stable, but extremely sensitive to moisture.
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