Synthesis and Molecular Structure of the Solvent‐Free [LiN(SiMe3)(2,6iPr2C6H3)]2 Dimer

Dietmar Kennepohl; Sally Brooker; In Memory: G.M. Sheldrick (1942–2025); Herbert W. Roesky

doi:10.1002/cber.19911241013

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Synthesis and Molecular Structure of the Solvent‐Free [LiN(SiMe3)(2,6iPr2C6H3)]2 Dimer

Chemische Berichte 124(10): 2223-2225

Article 1991 English

Abstract

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[LiN(SiMe 3 )Ar] 2 ( 1 , Ar = 2,6‐ i Pr 2 C 6 H 3 ) is prepared by the reaction of HN(SiMe 3 )Ar with n BuLi in n ‐hexane. This compound with an unusual structure contains a four‐membered [LiN] 2 heterocycle with two solvent‐free two‐coordinate Li centers. Its molecular structure represents the first solid‐state X‐ray analysis of an uncomplexed [LiN] 2 dimer.

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ChemInform Abstract: Synthesis and Molecular Structure of the Solvent‐Free (LiN(SiMe3)(2,6‐ iPr2C6H3))2 Dimer

Dietmar Kennepohl, Sally Brooker, In Memory: G.M. Sheldrick (1942–2025), Herbert W. Roesky

ChemInform

Synthesis and Molecular Structure of the Solvent‐Free [LiN(SiMe<sub>3</sub>)(2,6<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]<sub>2</sub> Dimer

Abstract

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Synthese und Struktur von Ph<sub>3</sub>PNRe(NC<sub>6</sub>H<sub>3</sub><i>i</i>Pr<sub>2</sub>;‐2,6)<sub>3</sub> ‐eine Aza‐Rhenium(VII)‐Verbindung

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Synthesis and Reactivity of Tris(imido)rhenium Complexes Containing Rhenium−Main Group Element Bonds. Silicon−Carbon Bond Activations of PhSiH<sub>3</sub>by Silyl Complexes

ChemInform Abstract: Synthesis and Molecular Structure of the Solvent‐Free (LiN(SiMe3)(2,6‐ iPr2C6H3))2 Dimer