Silver catalysed macrocyclic ether formation: crystal structure of [(CH2O)6Ag2][Ag][AsF6]3

Herbert W. Roesky; Egon Peymann; J. SCHIMKOWIAK; Mathias Noltemeyer; Waltraud Pinkert; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1039/c39830000981

Silver catalysed macrocyclic ether formation: crystal structure of [(CH2O)6Ag2][Ag][AsF6]3

Journal of the Chemical Society Chemical Communications: 981-981

Article 1983 English

Abstract

1 min read

Crystals containing the [(CH2O)6Ag2]2+ cation, which possesses approximate D3d symmetry with the two silver atoms each co-oriented by alternate oxygens of a novel twelve membered macrocyclic ether, were isolated from the reaction of (CH2O)3 with AgAsF6.

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Abstract

Discussion(0)

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