Cyclo-octasulphur as a ligand; preparation and X-ray crystal structure of [Ag(S8)2]AsF6

Herbert W. Roesky; Manfred Thomas; J. SCHIMKOWIAK; Peter G. Jones; Waltraud Pinkert; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1039/c39820000895

Cyclo-octasulphur as a ligand; preparation and X-ray crystal structure of [Ag(S8)2]AsF6

Journal of the Chemical Society Chemical Communications: 895-895

Article 1982 English

Abstract

1 min read

Reaction of AgAsF6 with S8 in liquid sulphur dioxide leads to [Ag(S8)2]AsF6, which contains cyclo-octasulphur ligands; the X-ray structure shows that the silver atoms achive distorted four-co-ordination by 1,3-linkages to two S8 rings.

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Cyclo-octasulphur as a ligand; preparation and X-ray crystal structure of [Ag(S8)2]AsF6

Abstract

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