One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)

D. Vodak; Matthew Braun; Lykourgos Iordanidis; Jacques Plévert; Michael R. Stevens; Larry W. Beck; John C. H. Spence; M. O’Keeffe; Omar M Yaghi

doi:10.1021/ja017683i

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One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)

Article 2002 en

Authors

DV
D. Vodak
MB
Matthew Braun
LI
Lykourgos Iordanidis

Abstract

1 min read

The reaction of pentaerythritol and tetraethylorthocarbonate at 260 degrees C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell [a = 9.167 A, b = 5.681 A, c = 5.880 A, beta = 90.0 degrees , space group I2] of hexagonally arranged spiro-oligomeric chains.

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