Synthesis and structure of [C3N2H5][Cu(H2PO4)2Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate

S. Neeraj; Thierry Loiseau; Cnr Rao; Anthony K. Cheetham

doi:10.1016/j.solidstatesciences.2004.05.007

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Synthesis and structure of [C3N2H5][Cu(H2PO4)2Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate

Solid State Sciences 6(10): 1169-1173

Article 2004 English

Abstract

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A new one-dimensional copper (II) phosphate, [C3N2H5][Cu(H2PO4)2Cl]·H2O, I, with pseudo-10-membered channels along the b-axis formed by the hydrogen bonded chains, containing imidazolium ions has been synthesized and characterized by single-crystal X-ray diffraction. The compound being the first example of an organically templated copper (II) phosphate, crystallizes in the monoclinic space group P21/n (No. 14) with a=8.9998(14) Å, b=7.0189(11) Å, c=18.986(3) Å; β=102.964(3)°; V=1168.8(3) Å3; Z=4. The copper chlorophosphate chains in I are topologically similar to those observed in fornacite and vauquelinite.

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Synthesis and structure of [C3N2H5][Cu(H2PO4)2Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate

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