A copolymer of poly(methyl methacrylate) with terpyridine units in the side chains was synthesized utilizing free-radical polymerization. The free terpyridine units were complexed with several different terpyridineruthenium mono-complexes, yielding metallo-supramolecular graft copolymers. The materials obtained were characterized by means of NMR and UV-vis spectroscopy as well as GPC. Characterization by thermal analysis revealed distinct differences between these new materials and the initial copolymer.
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