…are often invoked as catalytically competent intermediates in oxidative crosscouplings.T his Cover illustrates how two asteroids (CF 3 &Fligands) collide with Venus,traditionally associated to copper, assembling the organocopper(III) fluoride,[ Cu(CF 3 ) 3 F] À (2), which is depicted on the surface of the planet.In their Communication (e202319412), Julia Contreras-García, Noel Nebra et al. demonstrate the key role of 2 in C-CF 3 bond formation occurring through a2 e À redox shuttle.Graphic design by Pablo Falcón-Buedo.Aggregation-Induced Emission In their Research Article (e202313930), Terence T. W. Wong, Xuewen He,Ben Zhong Tang et al. demonstrate how co-aggregation of tetrazine molecules and fluorophores serves as as imple,fast, and convenient strategy for preparing fluorogenic nanoprobes.Polymer Chemistry An ew method to obtain hydrogel with at opologically cross-linked structure has been developed by Yuichi Ohya et al. in their Communication (e202317045).Topological gels possess structures that are cross-linked only via physical constraints. Heterogeneous CatalysisIn their Research Article (e202317526), Javier PØrez-Ramírez and co-workers demonstrate that 1-nm ruthenium particles supported on titania catalyze the hydrogenolysis to C 1 -C 45 alkanes of plastic caps used in soft drinks.
Chaitra Rao, Danielle E. Frodyma, Siddesh Southekal, Robert A. Svoboda, Adrian R. Black, Chittibabu Guda, Tomohiro Mizutani, Hans Clevers, Keith R. Johnson, Kurt W. Fisher, Robert E. Lewis
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