Darstellung und Struktur von Thallium(I)‐2,4,6‐tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig‐polymerem Aufbau

Preparation and Structure of Thallium(I) 2,4,6‐Tris(trifluoromethyl thiophenolate, a Compound with a Folded Polymeric Structure The title compound, thallium(I) 2,4,6‐tris(trifluoromethyl)thiophenolate (1) has been prepared by using either TlOEt and (CF 3 ) 3 C 6 H 2 SH or Tl 2 CO 3 and (CF 3 ) 3 C 6 H 2 SNa. A single X‐ray structural analysis shows a folded polymeric structure for 1 ; the crystal lattice incorporates half of a 1,4‐dioxane molecule per Tl atom. This compound has a surprisingly high kinetic stability compared to known thallium(I) thiolates.