Cobaloxime and DDT. X-Ray crystal structure of an unexpected vinyl-cobalt(III) complex

Reginald H. Prince; In Memory: G.M. Sheldrick (1942–2025); D.A. Stotter; Robin D. Taylor

doi:10.1039/c39740000854

Cobaloxime and DDT. X-Ray crystal structure of an unexpected vinyl-cobalt(III) complex

Journal of the Chemical Society Chemical Communications: 854-854

Article 1974 English

Abstract

1 min read

The crystal structure of the product of the reaction between bis(dimethylglyoximato)pyridinecobalt-(I) and the insecticide 1,1-bis-(p-chlorophenyl)-2,2,2-trichloroethane (p,p′-DDT) shows the presence of a chlorovinyl group σ-bonded to cobalt.

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Cobaloxime and DDT. X-Ray crystal structure of an unexpected vinyl-cobalt(III) complex

Abstract

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