ChemInform Abstract: Silyl and Diphenylsilylene Derivatives of (η5‐C5Me5)(PMe3)2Ru. Evidence for the Base‐Free Silylene Complex ((η5‐C5Me5)(PMe3)2Ru=SiPh2)+.

Daniel A. Straus; Chenyang Zhang; Grace E. Quimbita; Steven D. Grumbine; Richard H. Heyn; T Don Tilley; Arnold L. Rheingold; Steven J. Geib

doi:10.1002/chin.199029243

Back

ChemInform Abstract: Silyl and Diphenylsilylene Derivatives of (η5‐C5Me5)(PMe3)2Ru. Evidence for the Base‐Free Silylene Complex ((η5‐C5Me5)(PMe3)2Ru=SiPh2)+.

Article 1990 en

Abstract

1 min read

Abstract Both the Ru(II) and Ru(IV) silyl complexes (III) and (IV) are obtained from reaction of the trimethylsilylmethyl‐Ru(II) complex (I) with corresponding silanes as shown.

Discussion(0)

No comments yet. Be the first to comment.

Related publications

Article1990

Silyl and diphenylsilylene derivatives of (.eta.5-C5Me5)(PMe3)2Ru. Evidence for the base-free silylene complex [(.eta.5-C5Me5)(PMe3)2Ru:SiPh2]+

Daniel A. Straus, Cheng Zhang, Grace E. Quimbita, Steven D. Grumbine, Richard H. Heyn, T Don Tilley, Arnold L. Rheingold, Steven J. Geib

Article1997

Osmium Alkyl and Silyl Derivatives with Cyclopentadienyl(phosphine) and Pentamethylcyclopentadienyl(phosphine) Ligand Sets

Paulus W. Wanandi, T Don Tilley

Article1990

ChemInform Abstract: A Stable η2‐Silene Complex of Iridium: (η5‐C5Me5)(PMe3)Ir(η2‐CH2=SiPh2).

Brian K. Campion, Richard H. Heyn, T Don Tilley

Article1988

ChemInform Abstract: Preparation, Characterization, and X‐Ray Crystal Structure of an Acetonitrile‐Complexed Ruthenium Silylene.

Daniel A. Straus, T Don Tilley, Arnold L. Rheingold, Steven J. Geib

Article1987

ChemInform Abstract: Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X‐Ray Structures of d0 (η5‐C5Me5)Ta(SiMe3)Cl3 and d1 (η5‐C5Me5)Ta(SiMe3)(PMe3)Cl2.

John Arnold, David N. Shina, T Don Tilley, A.M. Arif