ChemInform Abstract: Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X‐Ray Structures of d0 (η5‐C5Me5)Ta(SiMe3)Cl3 and d1 (η5‐C5Me5)Ta(SiMe3)(PMe3)Cl2. — John Arnold (1987) | RDL Network
ChemInform Abstract: Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X‐Ray Structures of d0 (η5‐C5Me5)Ta(SiMe3)Cl3 and d1 (η5‐C5Me5)Ta(SiMe3)(PMe3)Cl2.
Abstract The trichloro title compound (II) prepared as shown is converted to the derivatives (III) and (IV) on treatment with one equiv. KOSiMe 3 or LiOtBu, or with 3 equiv. MeMgBr, respectively.
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