Publications

Boron-containing molybdenum silicides have been the focus of significant research of late due to their potentially superior low-temperature “pest” resistance and high-temperature oxidation resistance comparable to that of MoSi2-based silicides; however, like many ordered intermetallics, they are plagued by poor ductility and toughness properties. Of the various multiphase Mo–Si–B intermetallic systems available, alloys with compositions of Mo–12Si–8.5B (at.%), which contain Mo, Mo3Si, and T2 phases, are anticipated to have higher toughnesses because of the presence of the relatively ductile Mo phase. In this study, we examine the ambient to high (1300°C) temperature fracture toughness (R-curve) and fatigue-crack growth characteristics of Mo-12Si-8.5B, with the objective of discerning the salient mechanisms governing crack growth. It is found that this alloy displays a relatively high intrinsic (crack-initiation) toughness at 800 up to 1200°C (∼10 MPa√m), but only limited extrinsic R-curve (crack-growth) toughness. Although the lack of extrinsic toughening mechanisms is not necessarily beneficial to quasi-static properties, it does imply in a brittle material that it should show only minimal susceptibility to premature failure by fatigue, as is indeed observed at temperatures from ambient to 1300°C. Of particular significance is that both the fracture toughness and the threshold stress intensity for fatigue are increased with increasing temperature over this range. This remarkable property is related to a variety of toughening mechanisms that become active at elevated temperatures, specifically involving crack trapping by the α-Mo phase and extensive microcracking primarily in the Mo5SiB2 phase.

Utopia Point Bayesian Optimization (UPBO) was used to identify reaction conditions that are highly selective for the formation of N1 and N2-methyl-3-aryl pyrazole constitutional isomers. UPBO was used to explore a wide chemical space and identify basic reaction conditions for a typically acid-catalyzed Knorr pyrazole condensation. These studies revealed that selectivity in the reaction stems from a condition-dependent equilibrium of intermediates prior to dehydration. For the N2-methyl isomer reaction pathway, a hemiaminal intermediate was found to form reversibly under the reaction conditions, enabling a highly selective synthesis of the N2 isomer upon dehydrative workup. UPBO was able to successfully optimize conversion and selectivity simultaneously with search spaces of >1 million potential variable combinations without the need for high-performance computational resources.

Applications today rely on cloud databases for storing and querying time-series data. While outsourcing storage is convenient, this data is often sensitive, making data breaches a serious concern. We present Waldo, a time-series database with rich functionality and strong security guarantees: Waldo supports multi-predicate filtering, protects data contents as well as query filter values and search access patterns, and provides malicious security in the 3-party honest-majority setting. In contrast, prior systems such as Timecrypt and Zeph have limited functionality and security: (1) these systems can only filter on time, and (2) they reveal the queried time interval to the server. Oblivious RAM (ORAM) and generic multiparty computation (MPC) are natural choices for eliminating leakage from prior work, but both of these are prohibitively expensive in our setting due to the number of roundtrips and bandwidth overhead, respectively. To minimize both, Waldo builds on top of function secret sharing, enabling Waldo to evaluate predicates non-interactively. We develop new techniques for applying function secret sharing to the encrypted database setting where there are malicious servers, secret inputs, and chained predicates. With 32-core machines, Waldo runs a query with 8 range predicates over 2 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">18</sup> records in 3.03s, compared to 12.88s or an MPC baseline and 16.56s for an ORAM baseline. Compared to Waldo, the MPC baseline uses $9-82 \times$ more bandwidth between servers (for different numbers of records), while the ORAM baseline uses $20-152 \times$ more bandwidth between the client and server(s) (for different numbers of predicates).

Measurements of soil‐surface CO 2 fluxes are important for characterizing the carbon budget of boreal forests because these fluxes can be the second largest component of the budget. Several methods for measuring soil‐surface CO 2 fluxes are available: (1) closed‐dynamic‐chamber systems, (2) closed‐static‐chamber systems, (3) open‐chamber systems, and (4) eddy covariance systems. This paper presents a field comparison of six individual systems for measuring soil‐surface CO 2 fluxes with each of the four basic system types represented. A single system is used as a reference and compared to each of the other systems individually in black spruce (Picea mariana), jack pine (Pinus banksiana), or aspen (Populus tremuloides) forests. Fluxes vary from 1 to 10 μmol CO 2 m −2 s −1 . Adjustment factors to bring all of the systems into agreement vary from 0.93 to 1.45 with an uncertainty of about 10–15%.

We re-examine the classifications of supernovae (SNe) presented in the Lick Observatory Supernova Search (LOSS) volume-limited sample with a focus on the stripped-envelope SNe. The LOSS volume-limited sample, presented by Leaman et al. and Li et al., was calibrated to provide meaningful measurements of SN rates in the local universe; the results presented therein continue to be used for comparisons to theoretical and modeling efforts. Many of the objects from the LOSS sample were originally classified based upon only a small subset of the data now available, however, and recent studies have both updated some subtype distinctions and improved our ability to perform robust classifications, especially for stripped-envelope SNe. We re-examine the spectroscopic classifications of all events in the LOSS volume-limited sample (180 SNe and SN impostors) and update them if necessary. We discuss the populations of rare objects in our sample including broad-lined SNe Ic, Ca-rich SNe, SN 1987A-like events (we identify SN 2005io as SN 1987A-like here for the first time), and peculiar subtypes. The relative fractions of SNe Ia, SNe II, and stripped-envelope SNe in the local universe are not affected, but those of some subtypes are. Most significantly, after discussing the often unclear boundary between SNe Ib and Ic when only noisy spectra are available, we find a higher SN Ib fraction and a lower SN Ic fraction than calculated by Li et al.: spectroscopically normal SNe Ib occur in the local universe 1.7 ± 0.9 times more often than do normal SNe Ic.