Publications

Locally-active memristors blessed with an edge-of-chaos domain, which can be destabilized for generating action potentials, are natural candidates for emulating biological neurons. Pinpointing the edge-of-chaos domain, where neuromorphic behaviors may occur, is important for studying neuromorphic dynamics of memristors. This paper proposes a short-cut method for locating the edge-of-chaos domains in two kinds of generic memristors, and in several typical memristive 1-port circuits using only the Jacobian matrix in terms of their equations. Taking the Chua Corsage Memristor (CCM) and several CCM-based memristive 1-port circuits as examples, we verify the proposed new methods, and calculates their edge-of-chaos domains. Also, we carry out a complete classification of all the parameter regions of the CCM and several CCM-based memristive 1-port circuits, namely the locally-passive, locally-active but unstable, and edge-of-chaos domains, under both voltage and frequency control. Near the calculated edge-of-chaos domain, we uncover some new neuromorphic behaviors. To confirm the physical interpretations and predictions of the edge-of-chaos theorem, this paper presents an inexpensive electronic circuit realization of the complete set of equations defining the CCM using only off-the-shelf circuit components. When this poor-man’s memristor is connected to various linear passive R, L, C circuits, and a battery, the resulting circuit can be tuned to generate action potentials, and a garden variety of neuromorphic phenomena, including chaos. But the highlight of this paper is reserved for the CCM itself where the world’s first oscilloscope picture of a contiguous self-intersecting triple-branch DC V–I curve of the CCM is displayed in real time.

The Norian magmatic rocks of Jabuka, Brusnik and Vis Islands (Croatia) and their bearing on the evolution of Triassic magmatism in the Northern Mediterranean. The magmatic rocks from Jabuka, Brusnik, Vis Islands and the submerged Brusnik plateau have been investigated to define their age and genetic affinity, identifying their role in the geodynamics of the Adria Plate. The plutonic and lava flow samples have been characterized for their petrography, mineral chemistry, whole rock major and trace elements, and Sr and Nd isotopic compositions. The two samples with the freshest plagioclase crystals have been selected for ⁴⁰Ar/³⁹Ar analysis, which gave ages of 221.5 ± 2.5 Ma (Brusnik) and 227 ± 5 Ma (Jabuka), similar to those of the Triassic magmatism from the northern part of the Adria Plate and neighbouring territories. Geochemical and isotopic data suggest that the magmatism dominantly sourced from spinel peridotites variously metasomatized during pre-Mesozoic subduction events. Furthermore, the investigated rocks evidence interactions of the magmas with Mid-Late Triassic evaporites. The comparison with other coeval magmatic occurrences from the Adria Plate and its edges shows that the subduction signature of the Triassic within-plate magmatism is mainly related to the evolution of the upper mantle of the Adria Plate.

The goal of the "Opportunities for Catalysis Research in Carbon Management" workshop was to review within the context of greenhouse gas/carbon issues the current state of knowledge, barriers to further scientific and technological progress, and basic scientific research needs in the areas of H2 generation and utilization, light hydrocarbon activation and utilization, carbon dioxide activation, utilization, and sequestration, emerging techniques and research directions in relevant catalysis research, and in catalysis for more efficient transportation engines. Several overarching themes emerge from this review. First and foremost, there is a pressing need to better understand in detail the catalytic mechanisms involved in almost every process area mentioned above. This includes the structures, energetics, lifetimes, and reactivities of the species thought to be important in the key catalytic cycles. As much of this type of information as is possible to acquire would also greatly aid in better understanding perplexing, incomplete/inefficient catalytic cycles and in inventing new, efficient ones. The most productive way to attack such problems must include long-term, in-depth fundamental studies of both commercial and model processes, by conventional research techniques and, importantly, by applying various promising new physicochemical and computational approaches which would allow incisive, in situ elucidation of reaction pathways. There is also a consensus that more exploratory experiments, especially high-risk, unconventional catalytic and model studies, should be undertaken. Such an effort will likely require specialized equipment, instrumentation, and computational facilities. The most expeditious and cost-effective means to carry out this research would be by close coupling of academic, industrial, and national laboratory catalysis efforts worldwide. Completely new research approaches should be vigorously explored, ranging from novel compositions, fabrication techniques, reactors, and reaction conditions for heterogeneous catalysts, to novel ligands and ligation geometries (e.g., biomimetic), reaction media, and activation methods for homogeneous ones. The interplay between these two areas involving various hybrid and single-site supported catalyst systems should also be productive. Finally, new combinatorial and semicombinatorial means to rapidly create and screen catalyst systems are now available. As a complement to the approaches noted above, these techniques promise to greatly accelerate catalyst discovery, evaluation, and understanding. They should be incorporated in the vigorous international research effort needed in this field.

Metal-organic framework-808 has been functionalized with 11 amino acids (AA) to produce a series of MOF-808-AA structures. The adsorption of CO2 under flue gas conditions revealed that glycine- and DL-lysine-functionalized MOF-808 (MOF-808-Gly and -DL-Lys) have the highest uptake capacities. Enhanced CO2 capture performance in the presence of water was observed and studied using single-component sorption isotherms, CO2/H2O binary isotherm, and dynamic breakthrough measurements. The key to the favorable performance was uncovered by deciphering the mechanism of CO2 capture in the pores and attributed to the formation of bicarbonate as evidenced by 13C and 15N solid-state nuclear magnetic resonance spectroscopy studies. Based on these results, we examined the performance of MOF-808-Gly in simulated coal flue gas conditions and found that it is possible to capture and release CO2 by vacuum swing adsorption. MOF-808-Gly was cycled at least 80 times with full retention of performance. This study significantly advances our understanding of CO2 chemistry in MOFs by revealing how strongly bound amine moieties to the MOF backbone create the chemistry and environment within the pores, leading to the binding and release of CO2 under mild conditions without application of heat.

Abstract The formation of flexible self‐assembled monolayers (SAMs) in which an external trigger modifies the geometry of surface‐anchored molecules is essential for the development of functional materials with tunable properties. In this work, it is demonstrated that NO 2 ‐functionalized N‐heterocyclic carbene molecules (NHCs), which were anchored on Au (111) surface, change their orientation from tilted into flat‐lying position following trigger‐induced reduction of their nitro groups. DFT calculations identified that the energetic driving force for reorientation was the lower steric hindrance and stronger interactions between the chemically reduced NHCs and the Au surface. The trigger‐induced changes in the NHCs′ anchoring geometry and chemical functionality modified the work function and the hydrophobicity of the NHC‐decorated Au surface, demonstrating the impact of a chemically tunable NHC‐based SAM on the properties of the metal surface.

Halide perovskites have attracted much attention over the past 5 years as a promising class of materials for optoelectronic applications. However, compared to hybrid organic-inorganic perovskites, the study of their pure inorganic counterparts, like cesium lead halides (CsPbX3), lags far behind. Here, a catalyst-free, solution-phase synthesis of CsPbX3 nanowires (NWs) is reported. These NWs are single-crystalline, with uniform growth direction, and crystallize in the orthorhombic phase. Both CsPbBr3 and CsPbI3 are photoluminescence active, with composition-dependent temperature and self-trapping behavior. These NWs with a well-defined morphology could serve as an ideal platform for the investigation of fundamental properties and the development of future applications in nanoscale optoelectronic devices based on all-inorganic perovskites.