Bipolar transport polymers have been developed as host materials for electroluminescent devices by incorporating both electron-transporting and hole-transporting functionalities into copolymers. Two different copolymers having the same molecular weight (Mn ∼ 30 kg/mol) and the same fraction of electron-transporting monomers (fOXA = 0.50) have been synthesized in the form of random and diblock copolymers, respectively. The effect of molecular structure and film morphology of these bipolar polymers on device performance has been studied. For the diblock copolymers, pronounced phase segregation forming different nanomorphologies has been observed by modern microscopic techniques, which is not observed for the random counterparts under the same thin film preparation conditions. The results of single-layer polymer light emitting diodes (PLEDs) show that the nanophase separation morphology of diblock copolymers has a significant effect on device performance: lowering charge transport and facilitating the hole−electron recombination leads to a much higher quantum efficiency. Applying this high triplet block copolymer as host, a high external quantum efficiency of 5.4% at the brightness of 900 cd/m2 was achieved for single-layer PLEDs with a green-emitting complex dopant.
Mobile devices are increasingly equipped with multiple network interfaces with complementary characteristics. In particular, the Wi-Fi interface has high throughput and transfer power efficiency, but its idle power consumption is prohibitive. In this paper we present, Blue-Fi, a sytem that predicts the availability of the Wi-Fi connectivity by using a combination of bluetooth contact-patterns and cell-tower information. This allows the device to intelligently switch the Wi-Fi interface on only when there is Wi-Fi connectivity available, thus avoiding the long periods in idle state and significantly reducing the the number of scans for discovery.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
The gold-catalyzed [3+3]-cycloaddition reaction of propargyl esters and azomethine imines has been developed. The reaction provides a rapid entry into a wide range of substituted tetrahydropyridazine derivatives from simple starting materials. A stepwise mechanism involving addition of the 1,3-dipole to a gold-carbenoid intermediate is proposed.
Based on a simple circuit model of a tunneling phase logic (TPL) element that is driven by a sinusoidal voltage source and biased by a DC voltage source, we present simulations of operations in cellular nonlinear networks (CNN) that could potentially be used to perform general computations in 2D arrays of simple, locally connected nanoscale devices. Some examples are presented to demonstrate the image computation capability of TPL–CNN. In particular, we use a simple 2D TPL–CNN structure to perform edge detection, image enhancement and image segmentation. Some cellular automata (CA)-like behaviors of our 2D TPL-CNN are also presented.
In order to achieve significantly reduced power consumption, the transistor operating voltage needs to be reduced. To do this, a tunneling based transistor needs to rely on the density of states turn-on. Current can only flow when the conduction and valence bands overlap. If the band edges are ideal, one might expect an infinitely sharp turn on when the band edges overlap. Surprisingly, in a typical 3d bulk TFET, the nature of the turn on is actually quadratic in the gate voltage. Nevertheless, it is possible improve this if dimensionality is reduced. Consequently, we explored the nature of the band overlap for the various dimensionalities. We find that a 2d-2d pn junction brings us significantly closer to an ideal step function. Confining each side of the pn junction will also significantly increase the on state conductivity at low voltages.