493 publications from this institution
Abstract The titled compounds (3) were synthesized by the reaction of nitrile oxides with 1-azirines and also the reaction of aliphatic nitro compounds with dibenzoylmethane derivatives in the presence of acetyl chloride and sodium methoxide. The structure of 3 was established by single crystal X-ray analysis. A mechanism of the formation for 3 is proposed.
The authors have reported from experimental investigation that the use of closed stirrups, U-shaped stirrups and rod-shaped reinforcements as shear reinforcements in reinforced concrete (RC) beams results in clear differences in internal crack patterns and maximum strength. In this study, simulations of the experimental beams were performed using a three-dimensional rigid-body spring model, demonstrating that the behavior observed in the experiments is a mechanical phenomenon that can be reproduced numerically. Using the stress distribution over the beam cross section obtained from the analysis, the beam and arch action components of shear resistance are decoupled and considered from the perspective of the shear resistance mechanism. Further, through analysis of additional cases, the role of the upper and lower horizontal legs of the shear reinforcement, the effect of end anchorages on rod-shaped reinforcements were clarified.
