With respect to the aliphatic planar five-membered ring (r.m.s. deviation = 0.011 Å) of the title compound, C(15)H(13)N(3)O(2)S, the phenyl ring is aligned at 6.9 (1)° and the phenyl-ene ring at 2.4 (1)°, so that the three rings are nearly coplanar. The amino group has the N atom in a pyramidal geometry; the group is a hydrogen-bond donor to the sulfonyl O atom of one mol-ecule and to the ketonic O atom of another mol-ecule, resulting in the formation of a layer parallel to the bc plane.
Titanium dioxide nanoparticles are used in various applications, including environmental photocatalysis, solar cells and memory devices. In this study, we present the photodegradation of Rhodamine 6G and phenol red, employing heterogeneous photocatalytic process under solar irradiation. The experiments were carried out to study the effects of various parameters (i.e. the effect of the anchoring groups on the catalyst, concentration of the n-TiO2 semiconductor). The n-TiO2 was synthesized by a sol–gel process and characterized by SEM. When samples of n-TiO2 of different sizes were encapsulated with eriochromycine dye the quantum size effect is observed in the visible region of the spectrum. The rate of degradation was estimated from the residual concentration spectrophotometrically. Phenol red showed higher degradation than Rhodamine 6G which can be attributed to its sulfonic and hydroxyl anchoring groups. The photodegradation showed pseudo-first-order kinetics.
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In our study, three gemini dicationic surfactants with different methylene group spacer (16-6-16, 16-5-16 and 16-4-16) have been synthesized and characterized in solution by <sup>1</sup>H NMR spectroscopic technique. The implications of gemini micellar solution on ninhydrin and metal amino acid complex ([Cu(II)-Trp]<sup>+</sup>) were performed by the means of single-beam UV–visible spectroscopy. The absorbance was noted at regular time intermissions and values of rate constant (<i>k<sub>ψ</sub></i>) were determined by using a computer-based program. Synthesized surfactants proved as an efficient catalyst on the interaction of ninhydrin with metal amino acid complex as compared to conventional surfactant and aqueous systems. The required description regarding the implications of gemini dicationic surfactants are provided in the text in detail. The conductivity technique was applied in order to get critical micelle concentration (cmc) of geminis in the presence and absence of reactants. Catalytic results developed in gemini dicationic surfactant system were explained effectively by pseudo-phase model. Various thermodynamic quantities, <i>viz</i>., activation energy, <i>E</i><sub>a</sub>, activation enthalpy, <i>ΔH</i><sup>#</sup>, and activation entropy, <i>ΔS</i><sup>#</sup>, were obtained on interaction of ninhydrin with [Cu(II)-Trp]<sup>+ </sup>in gemini systems by applying Eyring equation. A detailed explanation about these evaluated parameters was also made.
New potential enzyme inhibitors, fluorine-substituted thiobarbituric acid derivatives (2, 3, 9, 8 and 12) and their fused/isolated heterocyclic nitrogen systems (5, 6, 10 and 14) have been obtained from heterocyclization of fluorinated N , N ʹ-disubstituted thiourea (1, 7 and 11) with malonic acid followed by ring closure reactions with primary nitrogen reagents. Structures of the synthesized products have been deduced from their elemental analysis and spectral data. Anti-HIV-1 and inhibition of cyclin-dependent kinase2 (CDK2) for cell tumor division for the synthesized compounds were also evaluated.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
