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An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
The Cover Feature shows UiO-66 and its different roles in catalysis, either as acid, basic, or bifunctional catalyst or as support. In their Review, A. Dhakshinamoorthy et al. describe that UiO-66 has become one of the most widely used metal-organic frameworks in heterogeneous catalysis as a result of its remarkable stability under solvothermal conditions. Furthermore, current understanding on the synthesis of this material using modulators has also allowed a considerable control on the crystallinity of this material and on the incorporation of structural defects. The present Review covers the use of UiO-66 as solid catalyst to promote organic reactions in the liquid phase, classified according to the role of UiO-66 as active component or as support of nanoparticles embedded within the internal pores. More information can be found in the Review by A. Dhakshinamoorthy et al. on page 899 in Issue 3, 2019 (DOI: 10.1002/cctc.201801452).
In the title compound, C(15)H(12)OS, the cyclo-hexene ring has a twisted boat conformation with the C atom between the ketone and methyl-ene atom and this methyl-ene C atom lying 0.280 (3) and 0.760 (3) Å, respectively, from the plane through the remaining four atoms (r.m.s. deviation = 0.004 Å). The dihedral angle between the benzene and thio-phene rings [21.64 (9)°] indicates an overall twist in the mol-ecule. The thio-phene S and ketone O atoms are anti, an orientation that allows the close approach of these atoms [3.3116 (17) Å] in the crystal structure and which leads to the formation of helical supra-molecular chains along the c axis.
