Publications

A study of the interaction of tetradecyltrimethylammonium bromide (TTAB) and levofloxacin hemihydrate (LFH) mixtures has been studied by conductivity measurement method in aqueous medium and in the presence of inorganic electrolyte (KNO3 and K2SO4)/urea at various temperatures (298.15−318.15 K) with typical gap of 5 K. For pure TTAB along with drug–TTAB mixture in aqueous as well as in salts/urea solution, a single critical micelle concentration (CMC) was noticed. The CMC values for LFH-TTAB mixtures in the presence of salts exhibited lower in magnitude as compared to aqueous solution. The ΔGm values were found to be negative in the entire cases signifying the spontaneous formation of micelles. Both ΔHm and ΔSm indicated that hydrophobic as well as electrostatic interactions were enhanced in the presence of electrolytes compared to an aqueous solution. Other thermodynamics variables such as transfer enthalpy (ΔHm.tr), transfer energy (ΔGm.tr), and transfer entropy (ΔS°m.tr) were evaluated and explained thoroughly.

Polyaniline nanofibers (PANINFs) have been facilely prepared by electrochemical polymerization of aniline monomers in acidic aqueous media without using any templates and surfactants. The subsequent treatment of such nanofibers with a AgNO3 aqueous solution leads to in situ chemical reduction of Ag+ on them to form Ag nanoparticles decorated PANINFs (AgNPs/PANINFs) nanocomposites. We investigated the catalytic activity and electrochemical properties of these nanocomposites. It is found that such nanocomposites exhibit excellent catalytic activity toward reduction of 4-nitrophenol to 4-aminophenol by NaBH4 and exhibit remarkable catalytic performance for H2O2 reduction. The enzymeless H2O2 sensor constructed using the nanocomposites shows a fast amperometric response time of less than 3 s. The linear range and detection limit are estimated to be from 0.1 mM to 60 mM (r = 0.998) and 1.7 μΜ at a signal-to-noise ratio of 3, respectively. We have fabricated a glucose biosensor by immobilizing glucose oxidase into the AgNPs/PANINFs-modified glassy carbon electrode for glucose detection. This sensor exhibits good response to glucose. The linear response range is estimated to be from 1 mM to 12 mM (r = 0.997) at −0.58 V. The detection limit is estimated to be 0.25 mM at a signal-to-noise ratio of 3.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Abstract We report on the facile one‐step hydrothermal preparation of a NiSe nanowire film on nickel foam (NiSe/NF) as a novel binder‐free electrode material for supercapacitors. This electrode delivers a high specific capacitance of 1790 F g −1 and an areal capacitance of 5.01 F cm −2 at a current density of 5 A g −1 .

Abstract Stabilization of zero-valent CuNi nanoparticles (NPs) supported on Cicer arietenum (CP) is reported here for the reduction and removal of persistent organic pollutants. The functional groups and interactions of NPs with the CP were determined by ATR-FTIR. The crystallinity, morphology, and the elemental composition of the samples were determined through powder XRD, FESEM, and EDS techniques, respectively. The XRD spectrum displayed a sharp crystalline peak at 43.9 for CuNi. The Cu and Ni zero-valent NPs displayed a peak at almost the same region, and thus, both the peaks are merged and appeared as a single peak. The chemical reduction/degradation of eight model pollutants, viz., 2-nitrophenol (ONP), 3-nitrophenol (MNP), 4-nitrophenol (PNP), 2,4-dinitrophenol (DNP), methyl orange (MO), congo red (CR), methylene blue (MB), and rhodamine B (RB) were carried out in the presence of NaBH 4 . The k app value of 0.1 mM 4NP was highest which was 1.8 × 10 −1 min −1 while the slowest rate was observed for CR and RB with k app 5.5 × 10 −3 and 5.4 × 10 −3 min −1 respectively. This article helps in the removal of toxic organic pollutants through green supported NPs.