4,218 publications from this institution
Nanocatalysts that possess large amounts of atoms on sharp corners and edges and high indexed sites are known to be more catalytically active. We report here on a novel yet simple method to synthesize in large yields a very active platinum nanocatalyst; the multiarmed nanostar single crystal. We utilize a seed mediated method using tetrahedral nanoparticles that are also synthesized by a new and simple technique. High-resolution TEM shows that the nanostar has many arms, varying from a few to over 30, whereby even the largest ones are found to have single-crystal structures. This strongly suggests that they are formed by a growth mechanism of the seed crystals and not by the aggregation of seed crystals, which should produce twinning planes. Due to the reduction reaction of ferrricyanide by thiosulfate, the nanostars are found to have an activation energy, which is nearly 60% of that of the tetrahedral seeds themselves, both having the same PVP capping agent. This is undoubtedly due to the multiarms with edges, corners, and the presence of high indexed facets in the nanostar catalyst.
Abstract Pb(Mg1/3Nb2/3)O3 (PMN)- and its solid solution with PbTiO3 (PT) is one of the lead-based relaxor ferroelectrics and has been the most widely studied materials because of their high dielectric constants and high electrostrictive coefficients. The potential impact of the thin film ferroelectric relaxors in the integrated actuators and sensing applications has stimulated research on the growth and characterization of thin films. Thin films have been made by pulsed-laser deposition (PLD), sol-gel and metalrganic chemical-vapor deposition. It is known that electrical properties may be strongly influenced by the microstructure of films and the interface structures between different phase in such heterostructure systems. In this paper, we report the investigation of interfacial mismatch and interface structure of epitaxial Pb(Mg1/3Nb2/3)O3 (90%)- PbTiO3 (10%) relaxor thin film by high resolution transmission electron microscopy (HRTEM). Thin film capacitors of Pb(Mg1/3Nb2/3)O3 (90%) - PbTiO3 (10%) (PMN-PT) were grown by PLD on (100)-oriented LaA1O3 (LAO) substrates. La0.5Sr0.5CoO3 (LSCO) layer was deposited as electrode. Cross-sectional transmission electron microscopy samples were prepared following the traditional procedures including cutting, gluing, polishing and ion milling.
Polyethylene terephthalate (PET) films' electret property was significantly enhanced after being treated with inductively coupled plasma (ICP). Based on this modified material, the triboelectric nanogenerators' (TENGs) transferred charges remained at 68.6% of the initial value after 400 000 cycles of contact-separation process, which was about three times that of the untreated samples.
Structure and Structural Evolution: Structure, Bonding and Properties. Sodium Chloride and Rutile Related Structure Systems. Perovskite and Related Structure Systems. Fluorite-Type and Related Structure Systems. From Structural Units of Materials Engineering via Soft-Chemistry. Structure Characterizations: Electron Crystallography for Structure Analysis. Structure Analysis of Functional Materials. Chemicals and Valence Structure Analysis of Functional Materials. Appendices: Physical Constants, Electron Wavelengths and Wave Numbers. Crystallographic Structure Systems. FORTRAN Program for Calculating Crystallographic Data. Electron Diffraction Patterns for Several Types of Crystal Structures. FORTRAN Program for Calculating Single Valence-Loss EELS Spectra in TEM. Index.
Large scale HgTe nanowires have been grown from Te nanowires by solution approach at low temperature. The widths are in the range 10–20 nm, with lengths up to 1µm. The nanowires have been characterized by uv - vis spectra, scanning electron microscopy, energy-disperse X-ray spectroscopy (EDS), transmission electron microscopy. The effects of growth temperature and time have been investigated and the best growth temperature is 80 – 90°C. The electric properties of HgTe nanowires thin film fabricated on glass substrates were investigated and showed Ohm contact.
The preparation of ordered arrays of metal hollow spheres via colloidal crystal templating is reported. A seeded growth technique for metal coatings on isolated colloids in solution and a confined template‐directed synthesis method for metal patterning were combined. The polymer colloidal crystal template was prepared and kept stable using a microchannel. 2D and 3D ordered microstructures of silver hollow spheres were obtained (see Figure).