The process of vanadium electrorefining in NaCl–KCl–VCl2 melts was investigated. The optimum conditions of refining were determined by varying cathodic current density, vanadium concentration in the melt and specific quantity of electricity passed through the cell. The total amount of impurities in the refined product was below 0.07 wt. % and the current efficiency was 0.95±0.03 g/Ah.
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