Using silyl protecting group to enable post-deposition C–C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces — Iris Berg (2021) | RDL Network
Using silyl protecting group to enable post-deposition C–C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces
Article 2021 en
Authors
IB
Iris Berg
LH
Lillian V. A. Hale
MC
Mazal Carmiel-Kostan
Abstract
1 min read
Alkyne-functionalized NHC ligands were protected by TIPS group that enabled surface-anchoring of NHCs with chemically-sensitive functionality and providing access, following TIPS removal, to on-surface Sonogashira cross–coupling reactions.
Shahar Dery, Suhong Kim, Gabriele Tomaschun, Iris Berg, Daniel Feferman, Albano Cossaro, Alberto Verdini, Luca Floreano, Thorsten Klüner, Dean Toste, Elad Gross
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