Two new molecular phosphorus sulphides: α-P4S4and β-P4S4; X-ray crystal structure of α-P4S4

Alison M. Griffin; Peter C. Minshall; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1039/c39760000809

Shared by

In Memory: G.M. Sheldrick (1942–2025)

Two new molecular phosphorus sulphides: α-P4S4and β-P4S4; X-ray crystal structure of α-P4S4

Journal of the Chemical Society Chemical Communications: 809-810

Article 1976 English

Authors

AG
Alison M. Griffin
PM
Peter C. Minshall
In Memory: G.M. Sheldrick (1942–2025)
University of Gottingen

Abstract

1 min read

α-P4S4 and β-P4S4 are formed quantitatively by the action of (Me3Sn)2S on α-P4S3I2 and β-P4S3I2 respectively; X-ray crystal structure analysis shows that α-P4S4 possesses D2d molecular symmetry in the crystal.

Related publications

Article1971

Preparation and molecular structure of a new isomer of P4S3I2: 3,5-di-iodo-2,6,7-trithia-1,3,4,5-tetraphosphabicyclo[2,2,1]heptane

G. J. Penney, In Memory: G.M. Sheldrick (1942–2025)

Journal of the Chemical Society A Inorganic Physical Theoretical

Article1984

Preparation and crystal structures of two phosphorus–sulphur rings: (PhP)3S3and (PhP)2S4

Cornelia Lensch, W. Clegg, In Memory: G.M. Sheldrick (1942–2025)

Journal of the Chemical Society. Dalton transactions

Article1984

Preparation and crystal structures of two phosphorus–sulphur rings: (RPS)4and (RPS2)2(R = C6H2Me3-2,4,6)

Cornelia Lensch, In Memory: G.M. Sheldrick (1942–2025)

Journal of the Chemical Society. Dalton transactions

Article1984

Synthesis and X-ray structure of [Ag2(Ph2X2)4][AsF6]2(X = S or Se); six-membered silver–sulphur and silver–selenium rings

Herbert W. Roesky, Thomas W. Gries, Peter G. Jones, K.‐L. WEBER, In Memory: G.M. Sheldrick (1942–2025)

Journal of the Chemical Society. Dalton transactions

Article1972

The crystal and molecular structure of bis{μ[(tri-fluoromethyl)selono]manganese tetracarbonyl}

Colin J. Marsden, In Memory: G.M. Sheldrick (1942–2025)

Journal of Organometallic Chemistry

Two new molecular phosphorus sulphides: α-P<sub>4</sub>S<sub>4</sub>and β-P<sub>4</sub>S<sub>4</sub>; X-ray crystal structure of α-P<sub>4</sub>S<sub>4</sub>

Abstract

Discussion(0)

Related publications

Preparation and molecular structure of a new isomer of P4S3I2: 3,5-di-iodo-2,6,7-trithia-1,3,4,5-tetraphosphabicyclo[2,2,1]heptane

Preparation and crystal structures of two phosphorus–sulphur rings: (PhP)<sub>3</sub>S<sub>3</sub>and (PhP)<sub>2</sub>S<sub>4</sub>

Preparation and crystal structures of two phosphorus–sulphur rings: (RPS)<sub>4</sub>and (RPS<sub>2</sub>)<sub>2</sub>(R = C<sub>6</sub>H<sub>2</sub>Me<sub>3</sub>-2,4,6)

Synthesis and X-ray structure of [Ag<sub>2</sub>(Ph<sub>2</sub>X<sub>2</sub>)4][AsF<sub>6</sub>]<sub>2</sub>(X = S or Se); six-membered silver–sulphur and silver–selenium rings

The crystal and molecular structure of bis{μ[(tri-fluoromethyl)selono]manganese tetracarbonyl}