Through-Space Conjugation: An Effective Strategy for Stabilizing Intramolecular Charge-Transfer States

Intramolecular charge transfer (ICT) has significant impacts on organic optoelectronic materials, photochemistry, biotechnology, and so on. However, it is hard to stabilize the ICT state because of the rapid nonradiative charge recombination process, which often quenches light emission. In this work, we use new foldamers of the protonated pyridine-modified tetraphenylethene derivatives that possess through-space conjugation (TSC) characters as the models to study the impact of TSC on the ICT state. Steady and transient spectroscopies illustrate that the lifetime of the ICT state in the molecule with strong TSC can be much longer than those of molecules without TSC, giving rise to a higher fluorescence quantum yield. By combining the theoretical calculations, we demonstrate that the strong TSC can stabilize the ICT state and slow the charge recombination rate by more efficiently dispersing charges. This is a conceptually new design strategy for functional optoelectronic materials that require more stable ICT states.