Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium

Hsueh‐Ju Liu; Micah S. Ziegler; T Don Tilley

doi:10.1039/c8dt01925h

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Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium

Article 2018 en

Abstract

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Dehydrochlorination of Cp*Ru(IPr)Cl leads to an unusual C–C bond activation, yielding a cyclometalated Ru complex bearing an NHC-C(sp2) ligand. Reactivity studies of cyclometalated Ru complexes were explored.

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