Synthesis, Structure, and Hydrosilylation Catalysis of a Chiral A-Frame Rhodium(I) Dimer with Cis Diphosphite Ligands

Santiago Ini; Allen G. Oliver; T Don Tilley; Robert G. Bergman

doi:10.1021/om010428m

Abstract

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This paper reports the synthesis and structure of two new dinuclear chiral rhodium(I) complexes which feature a "cis-A-frame" geometry and their use as catalysts for the hydrosilylation of aromatic ketones.

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