Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(<scp>ii</scp>) complexes

Wangyang Ma; Jingxuan Zhang; Zhenyang Lin; T Don Tilley; Qing Ye

doi:10.1039/c9dt03342d

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Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(<scp>ii</scp>) complexes

Article 2019 en

Abstract

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The first mononuclear cyclic (alkyl)(amino) carbene supported titanium(<sc>iii</sc>) complex [Cl2Ti(cAAC)2] featuring a small S–T energy gap has been synthesized and structurally characterized.

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Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(<scp>ii</scp>) complexes

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