Synthesis of (−)‐Octalactin A by a Strategic Vanadium‐Catalyzed Oxidative Kinetic Resolution

Alexander T. Radosevich; Vincent Chan; Hui‐Wen Shih; Dean Toste

doi:10.1002/ange.200800554

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Synthesis of (−)‐Octalactin A by a Strategic Vanadium‐Catalyzed Oxidative Kinetic Resolution

Article 2008 en

Abstract

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Beide Produkte der kinetischen Racematspaltung werden bei dem im Schema beschriebenen Spaltungs-Rekombinations-Ansatz zur enantioselektiven Totalsynthese von (−)-Octalactin A genutzt. Bn=Benzyl, TBS=tert-Butyldimethylsilyl.

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