Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

Amarajothi Dhakshinamoorthy; Abdullah Mohamed Asiri; Patricia Concepción; Hermenegildo Garcı́a

doi:10.1039/c7cc05221a

Back

Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

Article 2017 en

Abstract

1 min read

A convenient method for the synthesis of borasiloxanes from silanes and pinacolboranes using Cu3(BTC)2 as a heterogeneous catalyst in acetonitrile at 70 °C is reported. This procedure is more convenient than Ru and Pd based homogeneous catalysts because it avoids the use of noble metals, easy handling of starting materials and the catalyst can be reused.

Discussion(0)

No comments yet. Be the first to comment.

Related publications

Article2021

α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base

Amarajothi Dhakshinamoorthy, Mercedes Ãlvaro, Abdullah Mohamed Asiri

Article2023

Cu‐Doped Heterointerfaced Ru/RuSe2 Nanosheets with Optimized H and H2O Adsorption Boost Hydrogen Evolution Catalysis

Kai Wang, Jinhui Zhou, Mingzi Sun, Fangxu Lin, Bolong Huang, Fan Lv, Lingyou Zeng, Qinghua Zhang, Lin Gu, Mingchuan Luo, Shaojun Guo

Article2018

Ru Modulation Effects in the Synthesis of Unique Rod-like Ni@Ni2P–Ru Heterostructures and Their Remarkable Electrocatalytic Hydrogen Evolution Performance

Ying Liu, Suli Liu, Yu Wang, Qinghua Zhang, Lin Gu, Shuchen Zhao, Dongdong Xu, Yafei Li, Jianchun Bao, Zhihui Dai

Article2021

Construction of Dual‐Active‐Site Copper Catalyst Containing both CuN3 and CuN4 Sites

Yu Xiong, Shibin Wang, Wenxing Chen, Jian Zhang, Qiheng Li, Han‐Shi Hu, Lirong Zheng, Wensheng Yan, Lin Gu, Dingsheng Wang, Yadong Li

Article2022

Al3+ Dopants Induced Mg2+ Vacancies Stabilizing Single-Atom Cu Catalyst for Efficient Free-Radical Hydrophosphinylation of Alkenes

Qi Xu, Chenxi Guo, Beibei Li, Zedong Zhang, Yajun Qiu, Shubo Tian, Lirong Zheng, Lin Gu, Wensheng Yan, Dingsheng Wang, Jian Zhang

Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu<sub>3</sub>(BTC)<sub>2</sub> as a solid catalyst

Abstract

Discussion(0)

Related publications

α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base

Cu‐Doped Heterointerfaced Ru/RuSe<sub>2</sub> Nanosheets with Optimized H and H<sub>2</sub>O Adsorption Boost Hydrogen Evolution Catalysis

Ru Modulation Effects in the Synthesis of Unique Rod-like Ni@Ni<sub>2</sub>P–Ru Heterostructures and Their Remarkable Electrocatalytic Hydrogen Evolution Performance

Construction of Dual‐Active‐Site Copper Catalyst Containing both CuN<sub>3</sub> and CuN<sub>4</sub> Sites

Al<sup>3+</sup> Dopants Induced Mg<sup>2+</sup> Vacancies Stabilizing Single-Atom Cu Catalyst for Efficient Free-Radical Hydrophosphinylation of Alkenes