Synthesis of a Stable Aminosilanol and a Lithium Aminosilanolate with Cubane Structure
Angewandte Chemie International Edition 23(11): 891-892
Article 1984 English
Authors
OG
Onno Graalmann
UK
Uwe Klingebiel
WC
W. Clegg
Abstract
1 min read
Neither inter‐ nor intramolecular NH 3 ‐ or H 2 O‐cleavage takes place in the first stable aminosilanol 2 , formed on reaction of the chlorosilanol 1 with ammonia. 2 reacts with BuLi to give 3 , which is tetrameric in the gas phase and in the solid state. equation image
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