Synthesis and Structure of a Non‐Polymeric Molecule Containing Eleven Alternating Sulfur‐ and Nitrogen‐Atoms

In compound (2), which formally stands between (SN)x and the sulfur imides, the average SN bond length is 1.602 Å and is thus similar to that in (SN)x(1.611 Å). (2) is formed as orange needles from the blood-red (1) in acetoni-trile by cleavage of S4N4 and sulfur.