Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

Michael I. Lipschutz; T Don Tilley

doi:10.1039/c2cc32974c

Abstract

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A strictly two-coordinate nickel(II) bis(amido) complex has been prepared and its reactivity towards a variety of small molecules is described. Ni[N(SiMe(3))(DIPP)](2) reacts with DMAP and acetonitrile to form T-shaped three-coordinate complexes, and preliminary results show that Ni[N(SiMe(3))(DIPP)](2) is a catalyst for the hydrosilation of olefins with secondary silanes at ambient temperature.

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Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

Abstract

Discussion(0)

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