Synthesis and Chemistry of the 16-Electron Osmium Complex [OsBr(η5-C5Me5)(PiPr3)]

P.B. Glaser; T Don Tilley

doi:10.1002/1099-0682(200111)2001:11<2747::aid-ejic2747>3.0.co;2-b

Abstract

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The isolable 16-electron half-sandwich Os complex [OsBr(η5-C5Me5)(PiPr3)] has been synthesized and structurally characterized. This unsaturated complex binds N2 reversibly at low temperature as determined by IR and multinuclear NMR spectroscopy. The reactions of the title complex with CO, H2, PhSiH3, and its thermolysis in C6H6 are reported.

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Synthesis and Chemistry of the 16-Electron Osmium Complex [OsBr(η5-C5Me5)(PiPr3)]

Abstract

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Related publications

Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ru(PPr<sup>i</sup><sub>3</sub>)Cl

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