Synthesis and Characterization of Et<sub>2</sub>NM{OB[OSi(O<sup><i>t</i></sup>Bu)<sub>3</sub>]<sub>2</sub>}<sub>3</sub> (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials — Kyle L. Fujdala (2005) | RDL Network
Synthesis and Characterization of Et<sub>2</sub>NM{OB[OSi(O<sup><i>t</i></sup>Bu)<sub>3</sub>]<sub>2</sub>}<sub>3</sub> (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials
Abstract Two new transition metal complexes containing the –OB[OSi(O t Bu) 3 ] 2 ligand, Et 2 NM{OB[OSi(O t Bu) 3 ] 2 } 3 (M = Zr, Hf), are reported. These species are the 4 th and 5 th examples of complexes containing this recently reported borosiloxide ligand. Their use as potential molecular precursors to multi‐component oxide materials via the thermolytic molecular precursor (TMP) method is discussed.
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