Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2

Saravanakumar Ayyappan; Graciela Dı́az de Delgado; Anthony K. Cheetham; Gérard Férey; Cnr Rao

doi:10.1039/a905326c

Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2

Journal of the Chemical Society. Dalton transactions: 2905-2907

Article 1999 English

Abstract

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The hydrothermal synthesis and single crystal XRD characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2, is described; the structure contains PbO3, PbO4 and PbO5 polyhedra, each with stereochemically active lone pairs of electrons, and exhibits several types of channels.

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Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2

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