Stable Coordination Compounds of “Thiazyl Fluoride”: Structure of [Co(NSF)6]2+ in the Crystal

Bruno Buß; Peter G. Jones; Rüdiger Mews; Mathias Noltemeyer; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1002/anie.197902311

Stable Coordination Compounds of “Thiazyl Fluoride”: Structure of [Co(NSF)6]2+ in the Crystal

Angewandte Chemie International Edition 18(3): 231-231

Article 1979 English

Abstract

1 min read

“Thiazyl fluoride” (NSF), the simplest nitrogen-sulfur-fluorine compound, is unstable at room temperature. It has now been stabilized as [Co(NSF)6][AsF6]2. The pronounced shortening of the SF and the SN bonds on complexation is worthy of note.

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Abstract

Discussion(0)

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Abstract

Discussion(0)

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