Soluble Pt<sup>II</sup>-Containing Polymers Based on a 2,6-Bis(1<i>H</i>-1,2,3-triazol-4-yl)-4-ethynylpyridine Ligand — Benjamin Schulze (2017) | RDL Network
Soluble Pt<sup>II</sup>-Containing Polymers Based on a 2,6-Bis(1<i>H</i>-1,2,3-triazol-4-yl)-4-ethynylpyridine Ligand
Article 2017 en
Authors
BS
Benjamin Schulze
AW
Andreas Winter
CF
Christian Friebe
Abstract
1 min read
A soluble Pt<sup>II</sup>-acetylide polymer <b>6</b> was prepared in a supramolecular polymerization of a Pt<sup>II</sup>-chloro precursor complex <b>5</b>, which represents a self-complementary AB-type monomer. This new type of polymer combines the structural features of the common polyplatinynes and cationic Pt<sup>II</sup>-acetylide complexes. Though the photophysical and electrochemical properties of the material still need to be advanced, a versatile and straightforward method for the preparation of soluble, cationic Pt<sup>II</sup>-acetylide polymers with phosphorescent behavior is offered.
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