In this study, we explored several alternative functional forms to construct more accurate and more physical density coherence (DC) functionals for multiconfiguration density-coherence functional theory. Each functional is parameterized against the same database as used in our previous work. The best DC functional, which is called DC24, has a more physical interpretation, and-as a side benefit-it also has a mean unsigned error of 1.73 kcal/mol, which is a 9% improvement as compared to the previous functional. The article also contains a new definition of the unpaired electron density, which may be useful in other contexts as well.
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